Highly impact toughened and excellent flame-retardant polylactide/poly(butylene adipate-co-terephthalate) blend foams with phosphorus-containing and food waste-derived flame retardants.

Green polymeric foams are an important research topic for sustainable development. In this study, a natural multifunctional flame-retardant additive based on food waste was developed and evaluated for its ability to replace the commercial additives tricresyl phosphate (TCP) and trioctyl phosphate (TOP) in a polylactide/poly(butylene adipate-co-terephthalate) (PLA/PBAT) foam. A series of blend foams with additives were prepared by melt extrusion. According to the results, the blend foam with 20 phr of TCP showed the best combination of impact toughness and flame retardancy. TCP, however, poses health and environmental risks. Therefore, natural flame retardants (NFRs) were used to partially replace the commercial flame retardant (CFR). A combination of TCP and soybean residue (SB) produced an impact toughened and flame-retardant blend foam. When compared to the neat PLA/PBAT foam, the impact toughness of the best sample was increased by about 256 %. The optimal foam showed excellent flame resistance with a V-0 UL-94 rating and a high LOI value (31.8 %). SB has the potential to partially replace TCP as flame retardant and could be used in a broad range of PLA/PBAT foam applications.

Properties and flame retardancy of polylactide composites incorporating tricresyl phosphate and modified microcrystalline cellulose from oil palm empty fruit bunch waste.

One of the major environmental issues that have an impact on humans, animals, and their surroundings is plastic garbage. The use of biodegradable polymers in place of traditional plastics is one of the best solutions to this significant issue. The bio-circular-green (BCG) economic model is supported by the use of microcrystalline cellulose (MCC) as a bio-filler for polylactide (PLA) composites, which may also help to address the issue of improper plastic waste management. This study explores the chemical modification of MCC derived from oil palm empty fruit bunch waste (OPMC). Maleic anhydride-modified OPMC (MAMC) is successfully synthesized by a solvent-free and low temperature heating procedure. MAMC and tricresyl phosphate (TCP) were used as additives in PLA composites which were processed by melt extrusion and compression molding. Characterization studies confirmed the successful modification of MAMC and indicated that TCP played a crucial role as an effective plasticizer and flame retardant for PLA. All PLA/TCP composites showed significantly improved toughness and delayed ignition. The appropriate TCP level was 10 phr. The incorporation of TCP and MAMC resulted in a synergistic enhancement of impact strength and maintained excellent flame inhibition. Moreover, the thermal stability of the PLA composites increased with increments of MAMC.

Synergistic effect of microcrystalline cellulose from oil palm empty fruit bunch waste and tricresyl phosphate on the properties of polylactide composites.

Microcrystalline cellulose (MCC) was extracted from oil palm empty fruit bunch (OPEFB) waste by integrated chemical treatments of delignification, bleaching, and acidic hydrolysis. The obtained MCC (OPMC) and tricresyl phosphate (TCP) were used as additives for polylactide (PLA) composites. The influences of OPMC and TCP contents, separately and in combination, were evaluated on the properties of the composites. Characterization studies confirmed the successful extraction of OPMC from OPEFB waste. With regard to the properties of the PLA composite, the appropriate content of OPMC should be 5 phr. The good distribution of OPMC in the polymer matrix changed the failure behavior of the composite from brittle to ductile. All the PLA composites with TCP and OPMC showed flame inhibition and retarded ignition. The synergistic effect of TCP and OPMC resulted in outstanding improvement of impact strength and flame retardancy of composites. The impact toughness of PT10M5 increased to about 218.4 % and 72.3 % that of neat PLA and PT0M5, respectively. Moreover, PT10M5 achieved V-0 rating with high LOI (38.5 %). All these characteristics promise extended applications for PLA composite in bio, circular, and green (BCG) economies and electronics industries.

Fire-extinguishing characteristics and flame retardant mechanism of polylactide foams: Influence of tricresyl phosphate combined with natural flame retardant.

Extrusion and compression molding techniques were used to process polylactide (PLA) foams using a mixture blowing agent. Tricresyl phosphate (TCP) and natural flame retardants (NFR) from pumpkin (PK) and soybean (SB) were added to rigid PLA foams and the flame retardant properties of the foams were investigated. The effects of TCP content, types and amounts of NFR, and the ratio of TCP to NFR were determined on the physical, thermal and morphological characteristics of the foams. The fire-extinguishing characteristics and flame retardant mechanism of PLA foams with TCP were studied by thermogravimetric analysis-Fourier transform infrared (TGA-FTIR), scanning electron microscope (SEM), limiting oxygen index (LOI), and UL-94 techniques. The results revealed the efficiency of TCP as a flame retardant for PLA foams. Increased TCP levels contributed to a significant enhancement in fire-extinguishing characteristics. Phosphoric acid from thermal decomposition of TCP was a key factor in the proposed mechanism of flame retardation. Flame inhibition and retarded ignition of the PLA foams were achieved at all compositions of TCP and NFR. Due to the presence of compounds such as cellulose, phosphate, and silica, both PK and SB could be used as effective NFRs for PLA foams. All these characteristics promise extended applications for PLA foam in bio, circular, and green economies.